Mesitylene Mesitylene

Mesitylene Structural Formula

Structural formula

Business number 02XP
Molecular formula C9H12
Molecular weight 120.19
label

1,3,5-trimethylbenzene,

1,3,5-Trimethylbenzene,

thinner,

hydrocarbon solvents,

For organic synthesis

Numbering system

CAS number:108-67-8

MDL number:MFCD00008538

EINECS number:203-604-4

RTECS number:OX6825000

BRN number:906806

PubChem number:24867747

Physical property data

1. Properties: colorless liquid with special odor.

2. Boiling point (ºC, 101.3kPa): 162~164

3. Melting point (ºC): -45

4. Relative density (g/ mL, 20/4ºC): 0.8631

5. Relative density (g/mL, 25/4ºC): 0.8611

6. Relative vapor density (g/mL, air=1 ): 4.1

7. Refractive index (n20D): 1.4994

8 . Refractive index (25ºC): 1.49684

9. Viscosity (mPa·s, 20ºC): 1.154

10. Viscosity (mPa·s, 30ºC): 0.936

11. Flash point (ºC): 43

12. Heat of evaporation (KJ/mol, b.p.): 39.06

13. Heat of fusion (KJ/mol): 9.520

14. Heat of formation (KJ/mol, 25ºC, gas): -16.077

15. Heat of formation (KJ/mol, 25ºC, liquid): -63.572

16. Heat of combustion (KJ/mol, gas→liquid): 4979.82

17. Specific heat capacity (KJ/(kg·K), constant pressure): 1.25

18 . Critical temperature (ºC): 364.13

19. Critical pressure (MPa): 3.127

20. Conductivity (S/m, 25ºC): <1×10 -16

21. Vapor pressure (kPa, 48.82ºC): 1.33

22. Vapor pressure (kPa, 99.746ºC): 13.33

23. Vapor pressure (kPa, 141.387ºC): 53.33

24. Thermal conductivity (W/(m·K),-40ºC): 0.1704

25. Thermal conductivity Thermal conductivity (W/(m·K), 20ºC): 0.1586

26. Thermal conductivity (W/(m·K), 80ºC): 0.1402

27. Ignition point ( ºC): 531

28. Lower explosion limit (%, V/V): 1.3

29. Upper explosion limit (%, V/V): 13.1

30. Solubility: Insoluble in water, soluble in ethanol, ether and benzene.

31. Relative density (20℃, 4℃): 0.8651

32. Eccentricity factor: 0.399

33. Solubility parameter (J·cm-3)0.5: 18.007

34. van der Waals area (cm2</supThe boiling points are extremely similar (165.15), which is difficult to separate by distillation.

3.Isomerization method using mesitylene as raw material, the single-pass yield rate of1,3,5-trimethylbenzene obtained by fractionation21.6%, the purity is 95% and above, and the by-product is 4% -7% of tetramethylbenzene and 9% of xylene. Average reactor bed temperature260, pressure 2.35MPa, emptying 1.0h-1, reforming hydrogen and oil The molar ratio is 10: 1, and the catalyst is aluminum-hydrogen-deficient mordenite: copper: nickel: binding Agent=85.2: 0.5: 15. Under these conditions, the conversion rate of mesitylene is 46%, the selectivity is 47%, and mesitylene is produced in one pass The yield is 21.6%. Japan’s Mitsubishi Gas Company uses HF-BF3 to separate and isomerize xylene, and the by-product contains high concentrations of 1,3,5 –The high boiling substance of trimethylbenzene can be obtained by distillation and refinement.

4. Acetone is dehydrated and synthesized under the catalysis of sulfuric acid to 13%-15% This product can be obtained with a yield of span>. Cool 4600g (79mol) industrial acetone to 0-5 , add 4160mlConcentrated sulfuric acid, the temperature does not exceed 10. Add and stir for 3-4h, then leave at room temperature 18-24h. The product is steam distilled to separate 1,3,5-trimethylbenzene, and then washed with alkali and water, and collected by distillation210fraction, add 15g metal sodium, heated to near boiling point, evaporate 2/3 of the liquid, and distill the remainder to 210, efficient fractionation collection163-167Fraction, get 430-470g1,3,5-Trimethylbenzene.

5. Separation from coal tar and crude petroleum products And get.

Purpose

Organic synthetic raw materials, used to prepare trimesic acid, as well as antioxidants, epoxy resin curing agents, polyester resin stabilizers, Alkyd resin plasticizer, used to produce 2,4,6-trimethylaniline for the production of reactive brilliant blue, K- 3R and other dyes.

This article is from the Internet, does not represent the position of Toluene diisocyanate reproduced please specify the source.https://www.chemicalchem.com/archives/26773

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