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Main

Applications of Bis[2-(N,N-Dimethylaminoethyl)] Ether in Marine Corrosion-Resistant Coatings

Contents

  1. Introduction
    1.1 Background of Marine Corrosion
    1.2 Overview of Corrosion-Resistant Coatings
    1.3 Introduction to Bis[2-(N,N-Dimethylaminoethyl)] Ether (BDMAEE)
  2. Chemical Properties and Synthesis of BDMAEE
    2.1 Chemical Structure and Formula
    2.2 Physicochemical Properties
    2.3 Synthesis Methods
  3. Mechanisms of Corrosion Inhibition by BDMAEE in Marine Coatings
    3.1 Neutralization of Acidic Corrosive Species
    3.2 Formation of Protective Layer
    3.3 Improvement of Coating Adhesion and Barrier Properties
    3.4 Catalytic Effect on Resin Crosslinking
  4. Applications of BDMAEE in Marine Corrosion-Resistant Coatings
    4.1 Epoxy Resin Coatings
    4.2 Polyurethane Coatings
    4.3 Alkyd Resin Coatings
    4.4 Other Coating Systems
  5. Performance Evaluation of BDMAEE-Modified Marine Coatings
    5.1 Salt Spray Resistance Test
    5.2 Electrochemical Impedance Spectroscopy (EIS)
    5.3 Adhesion Test
    5.4 Water Absorption Test
    5.5 Mechanical Property Tests
  6. Influence of BDMAEE Concentration on Coating Performance
  7. Advantages and Disadvantages of Using BDMAEE
    7.1 Advantages
    7.2 Disadvantages
  8. Future Trends and Development Directions
  9. Safety and Environmental Considerations
  10. Conclusion
  11. References

1. Introduction

1.1 Background of Marine Corrosion

Marine environments present a uniquely aggressive corrosive environment due to the presence of high concentrations of chloride ions, dissolved oxygen, biological organisms, and varying temperatures. 🌊 These factors accelerate the electrochemical corrosion of metallic structures, leading to significant economic losses and safety concerns in industries such as shipping, offshore oil and gas, and coastal infrastructure. Marine corrosion is a complex process involving several factors:

  • High Salinity: Chloride ions penetrate protective layers and promote the formation of corrosion cells.
  • Dissolved Oxygen: Acts as a cathodic reactant, facilitating the corrosion reaction.
  • Temperature Variations: Affect the kinetics of corrosion reactions.
  • Biofouling: Marine organisms attach to surfaces, creating localized corrosion environments.
  • Erosion: Wave action and suspended particles physically erode protective coatings.

1.2 Overview of Corrosion-Resistant Coatings

Corrosion-resistant coatings are a crucial strategy for mitigating marine corrosion. These coatings act as a barrier between the metallic substrate and the corrosive environment, preventing or slowing down the corrosion process. Various types of coatings are used in marine applications, including:

  • Epoxy Coatings: Known for their excellent adhesion, chemical resistance, and mechanical properties.
  • Polyurethane Coatings: Offer good abrasion resistance, flexibility, and UV resistance.
  • Alkyd Coatings: Cost-effective and provide reasonable corrosion protection.
  • Inorganic Coatings: Such as zinc-rich coatings, provide sacrificial protection.

To further enhance the performance of these coatings, corrosion inhibitors are often added. These inhibitors can act by various mechanisms, such as forming a protective layer on the metal surface, neutralizing corrosive species, or slowing down the electrochemical reactions.

1.3 Introduction to Bis[2-(N,N-Dimethylaminoethyl)] Ether (BDMAEE)

Bis[2-(N,N-Dimethylaminoethyl)] Ether (BDMAEE), also known as 2,2′-Dimorpholinyldiethyl Ether, is a tertiary amine compound with the chemical formula C12H28N2O. It is a clear, colorless to slightly yellow liquid with a characteristic amine odor. BDMAEE is primarily used as a catalyst in the production of polyurethane foams and elastomers. However, it has also found applications as a corrosion inhibitor in various coating systems, particularly in marine environments. Its ability to neutralize acidic species, improve coating adhesion, and potentially form a protective layer on the metal surface makes it a valuable additive in corrosion-resistant coatings.

2. Chemical Properties and Synthesis of BDMAEE

2.1 Chemical Structure and Formula

The chemical structure of BDMAEE consists of an ether linkage with two dimethylaminoethyl groups attached to the ether oxygen. The chemical formula is C12H28N2O. The presence of two tertiary amine groups makes it a strong base and a reactive compound.

                      CH3   CH3
                      |     |
CH3-N-CH2-CH2-O-CH2-CH2-N-CH3
                      |     |
                      CH3   CH3

2.2 Physicochemical Properties

Property Value Reference
Molecular Weight 216.36 g/mol [1]
Appearance Clear, colorless to slightly yellow liquid [1]
Density 0.85 g/cm³ at 20°C [1]
Boiling Point 215-220°C [1]
Flash Point 85°C [1]
Viscosity 3.5 mPa·s at 25°C [1]
Solubility in Water Slightly soluble [1]
Vapor Pressure Low [1]

[1] Material Safety Data Sheet (MSDS) for BDMAEE (Example, specific MSDS document should be cited)

2.3 Synthesis Methods

BDMAEE can be synthesized through various methods, typically involving the reaction of an ether precursor with a dimethylamine derivative. Common synthetic routes include:

  • Reaction of Diethyl Ether with Dimethylaminoethanol: This method involves the reaction of diethyl ether with dimethylaminoethanol in the presence of a catalyst.
  • Reaction of Ethylene Oxide with Dimethylamine: This route involves the ring-opening reaction of ethylene oxide with dimethylamine, followed by dimerization.
  • Alkylation of Aminoethanol: This involves the alkylation of aminoethanol followed by etherification to form the final product.

The specific synthesis method used can influence the purity and yield of the BDMAEE product.

3. Mechanisms of Corrosion Inhibition by BDMAEE in Marine Coatings

BDMAEE exhibits several mechanisms that contribute to its corrosion inhibition properties in marine coatings:

3.1 Neutralization of Acidic Corrosive Species

The tertiary amine groups in BDMAEE are basic and can neutralize acidic species, such as hydrochloric acid (HCl) and sulfuric acid (H2SO4), which are often present in marine environments due to atmospheric pollution or microbial activity. The neutralization reaction reduces the concentration of these corrosive species, mitigating their detrimental effects on the metal substrate.

BDMAEE + HCl → BDMAEE·HCl (Ammonium Salt)

3.2 Formation of Protective Layer

BDMAEE can interact with the metal surface to form a protective layer that inhibits corrosion. This layer can be formed through several mechanisms:

  • Adsorption: BDMAEE molecules can adsorb onto the metal surface, forming a physical barrier that prevents the access of corrosive species.
  • Complexation: BDMAEE can complex with metal ions, forming a protective metal-organic complex on the surface.
  • Passivation: In some cases, BDMAEE can promote the formation of a passive oxide layer on the metal surface, further enhancing corrosion resistance.

The effectiveness of the protective layer depends on the type of metal, the concentration of BDMAEE, and the environmental conditions.

3.3 Improvement of Coating Adhesion and Barrier Properties

BDMAEE can improve the adhesion of the coating to the metal substrate. Good adhesion is crucial for preventing the ingress of corrosive species under the coating. The amine groups in BDMAEE can interact with the metal surface, forming strong bonds and improving adhesion. Furthermore, the presence of BDMAEE can influence the crosslinking density and morphology of the coating, leading to improved barrier properties against water and chloride ion penetration.

3.4 Catalytic Effect on Resin Crosslinking

BDMAEE is a well-known catalyst for polyurethane and epoxy resin curing. By accelerating the crosslinking reaction, BDMAEE can help to form a denser and more robust coating, which is less permeable to corrosive species. This catalytic effect contributes to improved corrosion resistance.

4. Applications of BDMAEE in Marine Corrosion-Resistant Coatings

BDMAEE has been incorporated into various types of marine corrosion-resistant coatings, including epoxy, polyurethane, and alkyd resin coatings.

4.1 Epoxy Resin Coatings

Epoxy resins are widely used in marine coatings due to their excellent adhesion, chemical resistance, and mechanical properties. Adding BDMAEE to epoxy coatings can further enhance their corrosion resistance. BDMAEE acts as a curing agent accelerator, promoting the crosslinking of the epoxy resin and improving the density and barrier properties of the coating. Furthermore, BDMAEE can improve the adhesion of the epoxy coating to the metal substrate and provide some level of corrosion inhibition through neutralization and protective layer formation.

Example Formulation:

Component Weight Percentage (%)
Epoxy Resin 40
Curing Agent 15
Pigment 25
Filler 15
BDMAEE 5

4.2 Polyurethane Coatings

Polyurethane coatings are known for their excellent abrasion resistance, flexibility, and UV resistance. BDMAEE is a commonly used catalyst in polyurethane coatings, accelerating the reaction between the polyol and isocyanate components. This results in a faster curing time and a denser coating. The addition of BDMAEE can also improve the corrosion resistance of polyurethane coatings by neutralizing acidic species and enhancing the barrier properties.

Example Formulation:

Component Weight Percentage (%)
Polyol 35
Isocyanate 25
Pigment 20
Additives 15
BDMAEE 5

4.3 Alkyd Resin Coatings

Alkyd resins are cost-effective and provide reasonable corrosion protection. Adding BDMAEE to alkyd coatings can improve their drying time and enhance their corrosion resistance. BDMAEE can act as a drier accelerator, promoting the oxidative crosslinking of the alkyd resin. It can also provide some level of corrosion inhibition through neutralization and protective layer formation.

Example Formulation:

Component Weight Percentage (%)
Alkyd Resin 50
Solvent 20
Pigment 15
Driers 10
BDMAEE 5

4.4 Other Coating Systems

BDMAEE can also be used in other coating systems, such as acrylic coatings and vinyl coatings, to improve their corrosion resistance and other properties.

5. Performance Evaluation of BDMAEE-Modified Marine Coatings

The performance of BDMAEE-modified marine coatings is typically evaluated using various techniques:

5.1 Salt Spray Resistance Test (ASTM B117)

The salt spray test is a standard method for evaluating the corrosion resistance of coatings. Coated samples are exposed to a continuous salt spray environment, and the degree of corrosion is assessed visually over time. The time to first rust and the overall rust rating are used to evaluate the performance of the coating.

5.2 Electrochemical Impedance Spectroscopy (EIS)

EIS is a powerful technique for characterizing the barrier properties of coatings. By measuring the impedance of the coating over a range of frequencies, information about the coating resistance, capacitance, and the diffusion of corrosive species can be obtained. Higher coating resistance and lower capacitance indicate better barrier properties.

5.3 Adhesion Test (ASTM D3359)

The adhesion test measures the strength of the bond between the coating and the substrate. The cross-cut tape test is a common method for assessing adhesion. A grid pattern is cut into the coating, and a piece of tape is applied and then removed. The amount of coating removed by the tape is used to evaluate the adhesion.

5.4 Water Absorption Test (ASTM D570)

The water absorption test measures the amount of water absorbed by the coating over time. Lower water absorption indicates better barrier properties and improved corrosion resistance.

5.5 Mechanical Property Tests

Mechanical property tests, such as tensile strength, elongation, and hardness, are used to evaluate the mechanical performance of the coating. These properties are important for ensuring the durability and long-term performance of the coating in marine environments.

Example Test Results:

Property Epoxy Coating (Control) Epoxy Coating with BDMAEE Improvement (%)
Salt Spray Resistance (h) 500 1000 100
Coating Resistance (EIS) 107 Ω·cm2 109 Ω·cm2 1000
Adhesion (ASTM D3359) 4B 5B
Water Absorption (%) 2.0 1.0 50

6. Influence of BDMAEE Concentration on Coating Performance

The concentration of BDMAEE in the coating formulation significantly affects the coating performance. An optimal concentration range exists, where BDMAEE provides the best balance of corrosion resistance, mechanical properties, and other desirable characteristics.

  • Low Concentration: Insufficient BDMAEE may not provide adequate corrosion inhibition or catalytic effect.
  • Optimal Concentration: Provides the best balance of properties, enhancing corrosion resistance, adhesion, and mechanical properties.
  • High Concentration: Excessive BDMAEE can lead to plasticization of the coating, reduced mechanical properties, and potential leaching of the additive from the coating matrix.

The optimal BDMAEE concentration typically ranges from 1% to 5% by weight of the resin solids, but this can vary depending on the specific coating formulation and application requirements.

7. Advantages and Disadvantages of Using BDMAEE

7.1 Advantages

  • Enhanced Corrosion Resistance: Provides improved corrosion protection in marine environments.
  • Improved Adhesion: Enhances the adhesion of the coating to the metal substrate.
  • Catalytic Effect: Accelerates the curing of polyurethane and epoxy resins.
  • Neutralization of Acidic Species: Neutralizes corrosive acidic species in the environment.
  • Potential for Protective Layer Formation: May contribute to the formation of a protective layer on the metal surface.

7.2 Disadvantages

  • Potential for Plasticization: High concentrations can plasticize the coating, reducing mechanical properties.
  • Odor: Can have a characteristic amine odor, which may be undesirable in some applications.
  • Leaching: May leach out of the coating over time, reducing its effectiveness.
  • Cost: Can increase the cost of the coating formulation.
  • Potential Toxicity: As with all chemicals, proper handling and safety precautions are required.

8. Future Trends and Development Directions

Future research and development efforts in the field of BDMAEE-modified marine coatings are likely to focus on:

  • Developing more effective and environmentally friendly corrosion inhibitors: Exploring alternative amine compounds or synergistic combinations of inhibitors.
  • Improving the long-term durability and performance of coatings: Investigating methods to prevent leaching and maintain the effectiveness of BDMAEE over extended periods.
  • Developing smart coatings that can respond to changes in the environment: Incorporating sensors and self-healing mechanisms into coatings.
  • Exploring the use of nanotechnology to enhance the properties of coatings: Incorporating nanoparticles to improve barrier properties, adhesion, and corrosion resistance.
  • Developing more sustainable and bio-based coating formulations: Utilizing renewable resources and reducing the reliance on petroleum-based materials.

9. Safety and Environmental Considerations

BDMAEE is a chemical substance and should be handled with care. Safety precautions should be taken to avoid skin and eye contact, inhalation of vapors, and ingestion. Wear appropriate personal protective equipment (PPE), such as gloves, goggles, and a respirator, when handling BDMAEE. Ensure adequate ventilation in the work area.

From an environmental perspective, it is important to minimize the release of BDMAEE into the environment. Follow proper waste disposal procedures and regulations. Consider using alternative corrosion inhibitors that are more environmentally friendly.

10. Conclusion

Bis[2-(N,N-Dimethylaminoethyl)] Ether (BDMAEE) is a valuable additive for enhancing the corrosion resistance of marine coatings. Its ability to neutralize acidic species, improve coating adhesion, catalyze resin crosslinking, and potentially form a protective layer on the metal surface makes it a versatile corrosion inhibitor. While BDMAEE offers several advantages, it is important to consider its potential disadvantages, such as plasticization, odor, and potential leaching. Future research and development efforts are focused on developing more effective, durable, and environmentally friendly corrosion inhibitors and coating formulations. By carefully considering the benefits and limitations of BDMAEE, formulators can develop high-performance marine coatings that provide long-term protection against corrosion.

11. References

(Please replace these with actual citations from scientific journals, books, and patents. Example format: [Author, A. A., Author, B. B., & Author, C. C. (Year). Title of article. Journal Name, Volume(Issue), Pages.])

  1. Jones, D. A. (1996). Principles and prevention of corrosion. Prentice Hall.
  2. Schweitzer, P. A. (2007). Corrosion engineering handbook. CRC press.
  3. Roberge, P. R. (2018). Handbook of corrosion engineering. McGraw-Hill Education.
  4. MSDS for BDMAEE (Specific document from supplier)
  5. ASTM B117 – Standard Practice for Operating Salt Spray (Fog) Apparatus
  6. ASTM D3359 – Standard Test Methods for Rating Adhesion by Tape Test
  7. ASTM D570 – Standard Test Method for Water Absorption of Plastics
  8. Relevant Patents related to BDMAEE in coatings. (e.g., US Patent Number XXXXXXX)
  9. Scientific journal articles on the use of tertiary amines as corrosion inhibitors. (e.g., Corrosion Science, Electrochimica Acta)

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